Bis(cyanato-κN)tetra­kis­(2,6-dimethyl­pyrazine-κN 4)nickel(II)

نویسندگان

  • Susanne Wöhlert
  • Inke Jess
  • Christian Näther
چکیده

Reaction of nickel(II) chloride with sodium cyanate and 2,6-di-methyl-pyrazine leads to single crystals of the title com-pound, [Ni(NCO)(2)(C(6)H(8)N(2))(4)]. The nickel(II) cation is located about a centre of inversion and is octa-hedrally coordinated by two cyanate anions and four 2,6-dimethyl-pyrazine ligands, forming discrete complexes.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Bis(2,6-dimethyl­pyrazine-κN 4)diiodidozinc(II)

In the title compound, [ZnI(2)(C(6)H(8)N(2))(2)], the Zn(II) ion is coordinated by two iodide anions and two N atoms from 2,6-dimethyl-pyrazine in a distorted tetra-hedral geometry.

متن کامل

Bis(dicyanamido-κN)tetra­kis­(pyridazine-κN)nickel(II)

Reaction of nickel(II) chloride with sodium dicyanamide and pyridazine leads to single crystals of the title compound, [Ni{N(CN)(2)}(2)(C(4)H(4)N(2))(4)], in which the Ni(II) cation is octa-hedrally coordinated by two dicyanamide anions and four pyridazine ligands into a discrete complex that is located on a center of inversion.

متن کامل

Coordination of bis­(pyrazol-1-yl)amine to palladium(II): influence of the co-ligands and counter-ions on the mol­ecular and crystal structures1

The structures of a series of complexes with general formula n[Pd(pza)X]Y·mH2O (n = 1, 2; X = Cl, Br, I, N3, NCS; Y = NO3, I, N3, [Pd(SCN)4]; m = 0, 0.5, 1) have been determined, where pza is the tridentate ligand bis-[2-(3,5-di-methyl-pyrazol-1-yl)eth-yl]amine, C14H23N5. In all complexes, {bis-[2-(3,5-di-methyl-pyrazol-1-yl-κN (2))eth-yl]amine-κN}chlorido-palladium nitrate, [Pd(pza)Cl]NO3, (1)...

متن کامل

Bis(dicyanamido-κN)tetra­kis­(pyridine-κN)nickel(II)

In the crystal structure of the title compound, [Ni(C(2)N(3))(2)(C(5)H(5)N)(4)], the Ni(II) cations are coordinated by four pyridine ligands and two dicyanamide anions into discrete complexes. The shortest Ni⋯Ni separation is 8.1068 (10) Å. The structure is pseudo-centrosymmetric and can also be refined in the space group C2/c in which both anionic ligands are strongly disordered and the refine...

متن کامل

Trans-bis­(3-tert-butyl­pyridine-κN)bis­(4-tert-butyl­pyridine-κN)bis­(thio­cyanato-κN)manganese(II)

The asymmetric unit of the title compound [Mn(NCS)(2)(C(9)H(13)N)(4)] consists of one Mn(II) cation located on a center of inversion, one thio-cyanato anion, one 3-tert-butyl-pyridine ligand and one 4-tert-butyl-pyridine ligand in general positions. The tert-butyl group of the 4-tert-butyl-pyridine ligand is disordered over two sets of sites in a 0.60:0.40 ratio. The Mn(II) cation is coordinate...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 68  شماره 

صفحات  -

تاریخ انتشار 2012